Florian Jaroschik

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Institut Charles Gerhardt Montpellier

Florian Jaroschik
Permanent - CR, Equipe D1
ICGM - UMR 5253
CC453
8 rue de l'Ecole Normale
34296 Montpellier cedex 5

florian.jaroschik@enscm.fr

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Thème de Recherche

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2021

Maxime Bouquin, Florian Jaroschik and Marc Taillefer
Versatile and base-free copper-catalyzed alpha-arylations of aromatic ketones using diaryliodonium salts,
Tetrahedron Lett. 2021, 75, 153208

2020

Moustapha Fortunato, Yves Gimbert, Elodie Rousset, Pedro Lameiras, Agathe Martinez, Sylvain Gatard, Richard Plantier-Royon and Florian Jaroschik
Diastereoselective Synthesis of Axially Chiral Xylose-Derived 1,3-Disubstituted Alkoxyallenes: Scope, Structure, and Mechanism,
J. Org. Chem. 2020, 85, 10681-10694

2019

Frank T. Edelmann, Joy H. Farnaby, Florian Jaroschik and Bradley Wilson
Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2018,
Coord. Chem. Rev. 2019, 398, 113005
Yujia Liu, Julien Bergès, Yassir Zaid, Fouad Ouazzani Chahdi, Arie Van Der Lee, Dominique Harakat, Eric Clot, Florian Jaroschik and Marc Taillefer
Aerobic and Ligand-Free Manganese-Catalyzed Homocoupling of Arenes or Aryl Halides via in Situ Formation of Aryllithiums,
J. Org. Chem. 2019, 84, 4413-4420

2018

Florian Jaroschik
Picking One out of Three: Selective Single C-F Activation in Trifluoromethyl Groups,
Chem.-Eur. J. 2018, 24, 14572-14582
Tarun Kumar, Amira Ben Hassine, Agathe Martinez, Dominique Harakat, Sylviane Chevreux, Fabien Massicot, Marc Taillefer, Jean-Bernard Behr, Jean-Luc Vasse and Florian Jaroschik
Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes,
J. Vis. Exp. 2018, 137, e57948

2017

Michaël Coffinet, Fabien Massicot, Jomy Joseph, Jean-Bernard Behr, Florian Jaroschik and Jean-Luc Vasse
(+)-Camphor-mediated kinetic resolution of allylalanes: a strategy towards enantio-enriched cyclohex-2-en-1-ylalane,
Chem. Commun. 2017, 53, 111-114
P. Santhini, S. Sarath Chand, Jubi John, R. Varma, Florian Jaroschik and K. Radhakrishnan
Lewis Acid Catalyzed Three-Component [3+2] Cycloaddition Reaction Using Pentafulvene as 2π Component: An Easy Way to Construct Pentaleno(1,2-b)indoles,
Synlett 2017, 28, 951-956
Florian Jaroschik, Manfred Penkhues, Bernard Bahlmann, Emmanuel Nicolas, Malte Fischer, Fabien Massicot, Agathe Martinez, Dominique Harakat, Marc Schmidtmann, Radhakrishnan Kokkuvayil Vasu, Jean-Luc Vasse and Rüdiger Beckhaus
Synthesis, Characterization and Reactivity of Formal 20 Electron Zirconocene-Pentafulvene Complexes,
Organometallics 2017, 36, 2004-2013
Parameswaran Sasikumar, Bernard Prabha, Sarngadharan Sarath Chand, Maniyamma Aswathy, Murali Madhukrishnan, Preethalayam Preethanuj, Eringathodi Suresh, Florian Jaroschik and Kokkuvayil Vasu Radhakrishnan
Lewis Acid Promoted Regioselective Double Hydro(hetero)arylation of 6,6'-Dialkyl-Substituted Pentafulvenes: A Facile Approach to Bisindole Derivatives,
Eur. J. Org. Chem. 2017, 2017, 4469-4474
Tarun Kumar, Fabien Massicot, Dominique Harakat, Sylviane Chevreux, Agathe Martinez, Klaudia Bordolinska, Preethanuj Preethalayam, Radhakrishnan Kokkuvayil Vasu, Jean-Bernard Behr, Jean-Luc Vasse and Florian Jaroschik
Generation of ϵ,ϵ-Difluorinated Metal-Pentadienyl Species through Lanthanide-Mediated C–F Activation,
Chem.-Eur. J. 2017, 23, 16460-16465
Michaël Coffinet, Jean-Bernard Behr, Florian Jaroschik, Dominique Harakat and Jean-Luc Vasse
Single or Synergistic Kinetic Resolutions of Chiral Allylalanes: Two Complementary Routes for the Asymmetric Synthesis of Syn Homoallylamines,
Org. Lett. 2017, 19, 6728-6731
Preethanuj Preethalayam, Syam K. Krishnan, Sreeja Thulasi, Sarath S. Chand, Jomy Joseph, Vijay Nair, Florian Jaroschik and K. Radhakrishnan
Recent Advances in the Chemistry of Pentafulvenes,
Chem. Rev. 2017, 117, 3930-3989

2016

Michaël Coffinet, Samantha Lamy, Florian Jaroschik and Jean-Luc Vasse
Cyclopent-2-enylaluminium as allylzinc precursor for the diastereoselective allylmetallation of non-racemic imines: applications to the synthesis of enantiomerically enriched heterocycles,
Org. Biomol. Chem. 2016, 14, 69-73
Sarath S. Chand, Greeshma Gopalan, P. Santhini, P. Preethanuj, Jubi John, Dominique Harakat, Florian Jaroschik and K. Radhakrishnan
Lewis Acid Catalyzed Regioselective Hydroheteroarylation of Pentafulvenes,
Org. Lett. 2016, 18, 964-967
Michaël Coffinet, Florian Jaroschik and Jean-Luc Vasse
Zirconocenes vs. Alanes: a Crucial Choice of the Allyl Source for Highly Diastereoselective Allylzincation of Nonracemic Chiral Imines,
Eur. J. Org. Chem. 2016, 2016, 2319-2327
Florian Jaroschik, Aurélien Momin, Agathe Martinez, Dominique Harakat, Louis Ricard, Xavier Frederic Le Goff and Grégory A Nocton
Synthesis and Characterization of 1,1'-Diphosphaplumbocenes: Oxidative Ligand Transfer Reactions with Divalent Thulium Complexes,
Organometallics 2016, 35, 2032-2038
Florian Jaroschik, Antoine Simonneau, Gilles Lemiere, Kevin Cariou, Nicolas Agenet, Hani Amouri, Corinne Aubert, Jean-Philippe Goddard, Denis Lesage, Max Malacria, Yves Gimbert, Vincent Gandon and Louis Fensterbank
Assessing Ligand and Counterion Effects in the Noble Metal Catalyzed Cycloisomerization Reactions of 1,6-Allenynes: a Combined Experimental and Theoretical Approach,
ACS Catal. 2016, 6, 5146-5160

2015

S. Sarath Chand, S. Sasidhar, Praveen Prakash, P. Sasikumar, P. Preethanuj, Florian Jaroschik, Dominique Harakat, Jean-Luc Vasse and K. Radhakrishnan
Lewis acid catalyzed C-3 alkylidenecyclopentenylation of indoles: an easy access to functionalized indoles and bisindoles,
RSC Adv. 2015, 5, 38075-38084
G. Bousrez, I. Déchamps, J -L. Vasse and Florian Jaroschik
Reduction of titanocene dichloride with dysprosium: access to a stable titanocene(II) equivalent for phosphite-free Takeda carbonyl olefination,
Dalton Trans. 2015, 44, 9359-9362
Rory P Kelly, Toby Bell, Rosalind Cox, Daisy Daniels, Glen Deacon, Florian Jaroschik, Peter Junk, Xavier Le Goff, Gilles Lemercier, Agathe Martinez, Jun Wang and Daniel Werner
Divalent Tetra- and Penta-phenylcyclopentadienyl Europium and Samarium Sandwich and Half-Sandwich Complexes: Synthesis, Characterization, and Remarkable Luminescence Properties,
Organometallics 2015, 34, 5624-5636
Jomy Joseph, Preethanuj Preethalayam, K. Radhakrishnan, Florian Jaroschik and Jean-Luc Vasse
Titanium and Zirconium Hydride-Catalyzed Regioselective Isomerization of 1,4-Dihydrofulvenes: Access to 1-Substituted 1,2-Dihydrofulvenes,
Org. Lett. 2015, 17, 6202-6205

2014

G. Deacon, Florian Jaroschik, P. Junk and Rory P Kelly
A divalent heteroleptic lanthanoid fluoride complex stabilised by the tetraphenylcyclopentadienyl ligand, arising from C–F activation of pentafluorobenzene,
Chem. Commun. 2014, 50, 10655-10657
Tomáš Strašák, Florian Jaroschik, Marek Maly, Jan Čermák, Jan Sykora, Radek Fajgar, Jindřich Karban and Dominique Harakat
Titanocene dichloride complexes bonded to carbosilane dendrimers via a spacer of variable length – Molecular dynamics calculations and catalysis of allylic coupling reactions,
Inorg. Chim. Acta 2014, 409, 137-146
Glen Deacon, Leslie Field, Keith Fisher, Florian Jaroschik, Danielle Kay, Thomas Maschmeyer and Anthony Masters
Fullerene matrices in the MALDI-TOF mass spectroscopic characterisation of organometallic compounds,
J. Organomet. Chem. 2014, 751, 482-492
Jomy Joseph, Florian Jaroschik, Dominique Harakat, K. Radhakrishnan, Jean-Luc Vasse and Jan Szymoniak
Titanium-Catalyzed Hydroalumination of Conjugated Dienes: Access to Fulvene-Derived Allylaluminium Reagents and Their Diastereoselective Reactions with Carbonyl Compounds,
Chem.-Eur. J. 2014, 20, 5433-5438
Glen Deacon, Florian Jaroschik, Peter Junk and Rory P Kelly
Bulky Group 2 Octaphenylmetallocenes and Direct Access to Calcium and Ytterbium Pseudo-Grignard Complexes,
Organometallics 2014, 34, 2369-2377

Florian Jaroschik, T. Kumar, F. Massicot, D. Harakat, S. Chevreux, A. Martinez, K. Bordolinska, P. Preethanuj, R. Kokkuvayil Vasu, J.-B. Behr, J.-L. Vasse,
Generation of ε,ε-difluorinated metal-pentadienyl species through lanthanide-mediated C-F activation
«XXVIII. Tage der Seltenen Erden – Terrae Rarae 2017», Tübingen, Allemagne, 4-6 octobre 2017,
Florian Jaroschik, T. Kumar, F. Massicot, J.-B. Behr, J.-L. Vasse, K. V. Radhakrishnan,
New C-F activation reactions involving metallic lanthanides
«SCF Grand Est 8», Mulhouse, France, 10-12 mai 2017,
Florian Jaroschik, A. Delon, N. Aubry, A. Tamboura, Q. Gil, M. Graiche, C. Brusa, M. Muzard, S. Gatard, R. Plantier-Royon, C. Rémond,
Synthèse et applications d’allènes et de phospholes chiraux à base de xylose issu de la biomasse
«Journées Condorcet 2016», Gembloux, Belgique, 05-06 juillet 2016,
Florian Jaroschik,
New transformations based on elemental lanthanides: from the reduction of metallacyclopentadienes to C-F activation
«Rare Earths 2016», Sapporo, Japon, 5-10 juin 2016,
Florian Jaroschik, G. B. Deacon, P. C. Junk, R. P. Kelly,
Synthesis of divalent organolanthanoid complexes carrying tetra and pentaphenylcyclopentadienyl ligands
«COST EuFEN 4 meeting», Lisbonne, Portugal, 11-12 avril 2015,
Florian Jaroschik, G. B. Deacon, P. C. Junk, R. P. Kelly,
Complexes organometalliques de lanthanides à base de ligands tetra et pentaphenylcyclopentadienyles : Synthèse, activation C-F et luminescence
«Journées de chimie de coordination de la SCF 2015», Bordeaux, France, 29-30 janvier 2015,
Florian Jaroschik, G. Bousrez, D. Harakat, I. Dechamps, J.-L. Vasse, J. Szymoniak,
Reducing titanocene dichloride with lanthanides: new insights and application in carbonyl olefination
«XXVI. Tage der Seltenen Erden – Terrae Rarae 2014», Cologne, Allemagne, 06-08 juillet 2014,

Institut Charles Gerhardt Montpellier - Direction

UMR 5253 - CNRS/UM/ENSCM

Pôle Chimie Balard Recherche
CC 043 - 1919 route de Mende
34293 Montpellier cedex 5
Tel: +33 (0)4 67 61 36 14
Email: direction@icgm.fr

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