Marc Taillefer

CNRS Research Director

2018 - .... : President of the French Chemical Society (SCF)
2018 - .... : Publication Director of the Actualité Chimique
2017 - .... : École Nationale Supérieure de Chimie de Paris - Member of the Scientific Council
2012 - 2015 : President of the Organic Chemistry Division of the SCF
2009 - 2015 : Vice President of the French Chemical Society (SCF)
2007 - 2012 : Institut Charles Gerhardt Montpellier (ICGM) - Member of the Institute's Council
2004 - 2008 : ENSCMontpellier - Member of the Scientific Council
2004 - 2012 : General Secretary of ADER Languedoc Roussillon (Research & development)
2001 - 2004 : ENSCMontpellier - Member of the Board of Directors

About

Institut Charles Gerhardt Montpellier

Marc Taillefer
Permanent - DR, Equipe D1
ICGM - UMR 5253
CC453
8 rue de l'Ecole Normale
34296 Montpellier cedex 5

marc.taillefer@enscm.fr

2004-present CNRS Research Director / Team Leader Ecole Nationale Supérieure de Chimie de Montpellier
1992-2004 CNRS Research Fellow Ecole Nationale Supérieure de Chimie de Montpellier
1990-1991 Postdoc, Technische Universität München with Prof. W. A. Herrmann
1986-1989 Ph.D., University Paul Sabatier, Toulouse with Dr. I. Tchatchenko and Dr. J. J. Brunet

Grand prix Emile JungFleisch Académie des sciences - French Academy of Sciences 2017
European Sustainable Chemistry Award, 2012
Clavel-Lespiau Prize from the Fench Academy of Science, 2010
"Innovation: Research/Industry" Award - ADER Languedoc-Roussillon, 2003

Research Interests

Synthesis, reactivity and applications of phosphonium ylides
Copper or iron-catalyzed arylation of nucleophiles (C-N, C-O and C-C bond formation)
Catalyzed reduction of unsaturated compounds - Mechanistic studies

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2021

Rémi Blieck, Sébastien Lemouzy, Arie Van Der Lee, Marc Taillefer and Florian Monnier
Synergistic Copper/Enamine Catalysis for the Regio-, Stereo-, and Enantioselective Intermolecular alpha-Addition of Aldehydes to Allenamides,
Org. Lett. 2021, 23, 9199-9203
Lucas Pages, Sébastien Lemouzy, Marc Taillefer and Florian Monnier
Easy Access to Allylic Sulfones Through Transition-Metal-Free Hydrosulfonylation Of Allenes,
J. Org. Chem. 2021, 86, 15695-15701
Maxime Bouquin, Florian Jaroschik and Marc Taillefer
Versatile and base-free copper-catalyzed alpha-arylations of aromatic ketones using diaryliodonium salts,
Tetrahedron Lett. 2021, 75, 153208
Alexis Prieto and Marc Taillefer
Visible-Light Decatungstate/Disulfide Dual Catalysis for the HydroFunctionalization of Styrenes,
Org. Lett. 2021, 23, 1484-1488

2020

Rémi Blieck, Marc Taillefer and Florian Monnier
Metal-Catalyzed Intermolecular Hydrofunctionalization of Allenes: Easy Access to Allylic Structures via the Selective Formation of C-N, C-C, and C-O Bonds,
Chem. Rev. 2020, 120, 13545-13598

2019

Janet Bahri, Nour Tanbouza, Thierry Ollevier, Marc Taillefer and Florian Monnier
Hydrogen-Bond-Promoted Metal-Free Hydroamination of Alkynes,
Synlett 2019, 30, 2086-2090
Racha Abed Ali Abdine, Gracjan Kurpik, Anna Walczak, Sultan Abu A. Aeash, Artur R. Stefankiewicz, Florian Monnier and Marc Taillefer
Mild temperature amination of aryl iodides and aryl bromides with aqueous ammonia in the presence of CuBr and pyridyldiketone ligands,
J. Catal. 2019, 376, 119-122
Rémi Blieck, Marc Taillefer and Florian Monnier
Copper-Catalyzed Hydrocarboxylation of N-Allenyl Derivatives,
J. Org. Chem. 2019, 84, 11247-11252
Yujia Liu, Julien Bergès, Yassir Zaid, Fouad Ouazzani Chahdi, Arie Van Der Lee, Dominique Harakat, Eric Clot, Florian Jaroschik and Marc Taillefer
Aerobic and Ligand-Free Manganese-Catalyzed Homocoupling of Arenes or Aryl Halides via in Situ Formation of Aryllithiums,
J. Org. Chem. 2019, 84, 4413-4420
Yassir Zaid, Cleve Dionel Mboyi, Martin Pichette Drapeau, Lea Radal, Fouad Ouazzani Chahdi, Youssef Kandri Rodi, Thierry Ollevier and Marc Taillefer
Transition-Metal-Free α-Vinylation of Enolizable Ketones with β-Bromostyrenes,
Org. Lett. 2019, 21, 1564-1568
Rémi Blieck, Luca Alessandro Perego, Ilaria Ciofini, Laurence Grimaud, Marc Taillefer and Florian Monnier
Copper-Catalysed Hydroamination of N-Allenylsulfonamides: The Key Role of Ancillary Coordinating Groups,
Synthesis 2019, 51, 1225-1234

2018

Martin Pichette Drapeau, Anis Tlili, Yassir Zaid, Dounia Toummini, Fouad Ouazzani Chahdi, Jean-Marc Sotiropoulos, Thierry Ollevier and Marc Taillefer
Transition-Metal-Free Synthesis of Biarylmethanes from Aryl Iodides and Benzylic Ketones,
Chem.-Eur. J. 2018, 24, 17449-17453
Tarun Kumar, Amira Ben Hassine, Agathe Martinez, Dominique Harakat, Sylviane Chevreux, Fabien Massicot, Marc Taillefer, Jean-Bernard Behr, Jean-Luc Vasse and Florian Jaroschik
Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes,
J. Vis. Exp. 2018, 137, e57948
Remi Blieck, Racha Abed Ali Abdine, Marc Taillefer and Florian Monnier
Regio- and Stereoselective Copper-Catalyzed Allylation of 1,3-Dicarbonyl Compounds with Terminal Allenes,
Org. Lett. 2018, 20, 2232-2235

2017

Yujia Liu, Vincent Blanchard, Gregory Danoun, Zhaoyang Zhang, Anis Tlili, Wenlong Zhang, Florian Monnier, Arie Van Der Lee, Jincheng Mao and Marc Taillefer
Copper-Catalyzed Sonogashira Reaction in Water,
ChemistrySelect 2017, 2, 11599-11602
Luca Alessandro Perego, Rémi Blieck, Julie Michel, Ilaria Ciofini, Laurence Grimaud, Marc Taillefer and Florian Monnier
Copper-Catalyzed Hydroamination of N -Allenylazoles: Access to Amino-Substituted N-Vinylazoles, Access to Amino-Substituted N-Vinylazoles,
Adv. Synth. Catal. 2017, 359, 4388-4392
Luca Alessandro Perego, Rémi Blieck, Antoine Groué, Florian Monnier, Marc Taillefer, Ilaria Ciofini and Laurence Grimaud
Copper-Catalyzed Hydroamination of Allenes from Mechanistic Understanding to Methodology Development,
ACS Catal. 2017, 7, 4253-4264

2016

Armelle Ouali and Marc Taillefer
Grignard reagents and Copper,
Physical Science Reviews 2016, 1, 20160037
Indira Fabre, Luca Alessandro Perego, Julien Bergès, Ilaria Ciofini, Laurence Grimaud and Marc Taillefer
Antagonistic Effect of Acetates in C–N Bond Formation with In Situ Generated Diazonium Salts: A Combined Theoretical and Experimental Study,
Eur. J. Org. Chem. 20165887-5896
Rémi Blieck, Janet Bahri, Marc Taillefer and Florian Monnier
Copper-Catalyzed Hydroamination of Terminal Allenes,
Org. Lett. 2016, 18, 1482-1485
Florian Monnier and Marc Taillefer
From Ruthenium to Copper: A la carte Tools for the Synthesis of Molecules of Interest,
Chimia 2016, 70, 53-60
Stephen Hyde, Janis Veliks, Benoît Liégault, David Grassi, Marc Taillefer and Véronique Gouverneur
Copper-Catalyzed Insertion into Heteroatom–Hydrogen Bonds withTrifluorodiazoalkanes,
Angew. Chem.-Int. Edit. 2016, 55, 3785-3789

2015

Janet Bahri, Rémi Blieck, Bassem Jamoussi, Marc Taillefer and Florian Monnier
Hydroamination of terminal alkynes with secondary amines catalyzed by copper, regioselective access to amines,
Chem. Commun. 2015, 51, 11210-11212
Janet Bahri, Bassem Jamoussi, Arie Van Der Lee, Marc Taillefer and Florian Monnier
Copper-Catalyzed Hydroamination of Alkynes with Aliphatic Amines, Regioselective Access to (1E,3E)-1,4-Disubstituted-1,3-dienes,
Org. Lett. 2015, 17, 1224-1227
Martin Pichette Drapeau, Indira Fabre, Laurence Grimaud, Ilaria Ciofini, Thierry Ollevier and Marc Taillefer
Transition-Metal-Free α-Arylation of Enolizable Aryl Ketones and Mechanistic Evidence for a Radical Process,
Angew. Chem.-Int. Edit. 2015, 36, 10587-10591
Amélie Pialat, Julien Bergès, Axel Sabourin, Robin Vinck, Benoit Liegault and Marc Taillefer
Iodine(III)-Mediated para-Selective Direct Imidation of Anilides,
Chem.-Eur. J. 2015, 21, 10014-10018

2014

Dounia Toummini, Anis Tlili, Julien Bergès, Fouad Ouazzani and Marc Taillefer
Copper-Catalyzed Arylation of Nitrogen Heterocycles from Anilines under Ligand-Free Conditions,
Chem.-Eur. J. 2014, 20, 14619-14625
Enrico Emer, Jack Twilton, Matthew Tredwell, Samuel Calderwood, Lee Collier Thomas, Benoit Liegault, Marc Taillefer and Veronique Gouverneur
Diversity-Oriented Approach to CF₃CHF-, CF₃CFBr-, CF₃CF₂-, (CF₃)₂CH-, and CF₃(SCF₃)CH-Substituted Arenes from 1-(Diazo-2,2,2-trifluoroethyl)arenes,
Org. Lett. 2014, 16, 6004-6007
Jorge Ballester, Anne-Marie Caminade, Jean Pierre Majoral, Marc Taillefer and Armelle Ouali
Efficient and eco-compatible transition metal-free Oppenauer-type oxidation of alcohols,
Catal. Commun. 2014, 47, 58-62
Jorge Ballester, Jérémie Gatignol, Guntran Schmidt, Carole Alayrac, Annie-Claude Gaumont and Marc Taillefer
A Copper-Catalyzed Variant of the Michaelis-Arbuzov Reaction,
ChemCatChem 2014, 6, 1549-1552
Martin Pichette Drapeau, Thierry Ollevier and Marc Taillefer
On the Frontier Between Nucleophilic Aromatic Substitution and Catalysis,
Chem.-Eur. J. 2014, 20, 5231-5236

2013

Emilie Racine, Florian Monnier, Jean-Pierre Vors and Marc Taillefer
Direct N-cyclopropylation of secondary acyclic amides promoted by copper,
Chem. Commun. 2013, 49, 7412-7414
Dounia Toummini, Fouad Ouazzani and Marc Taillefer
Iron-Catalyzed Homocoupling of Aryl Halides and Derivatives in the Presence of Alkyllithiums,
Org. Lett. 2013, 15, 4690-4693
Jérémie Gatignol, Carole Alayrac, Jean-François Lohier, Jorge Ballester, Marc Taillefer and Annie-Claude Gaumont
Copper-Catalyzed Synthesis of 1,3-Butadienylphosphine Oxides and Chemoselective Phosphoryl Reduction to Stereodefined 1,3-Butadienylphosphines,
Adv. Synth. Catal. 2013, 355, 2822-2826
Guillaume Lefèvre, Anis Tlili, Marc Taillefer, Carlo Adamo, Ilaria Ciofini and Anny Jutand
Discriminating role of bases in diketonate copper(I)- catalyzed C-O couplings, phenol versus diarylether,
Dalton Trans. 2013, 42, 5348-5354
Lucie Routaboul, Fabien Toulgoat, Jérémie Gatignol, Jean-François Lohier, Brigitte Norah, Olivier Delacroix, Carole Alayrac, Marc Taillefer and Annie-Claude Gaumont
Iron-Salt-Promoted Highly Regioselective α and β Hydrophosphination of Alkenyl Arenes,
Chem.-Eur. J. 2013, 19, 8760-8764
Amélie Pialat, Benoit Liegault and Marc Taillefer
Oxidative para-Triflation of Acetanilides,
Org. Lett. 2013, 15, 1764-1767

2012

Guillaume Lefèvre, Grégory Franc, Anis Tlili, Carlo Adamo, Marc Taillefer, Ilaria Ciofini and Anny Jutand
Contribution to the Mechanism of Copper-Catalyzed C-N and C-O Bond Formation,
Organometallics 2012, 31, 7694-7707
Grégory Danoun, Anis Tlili, Florian Monnier and Marc Taillefer
Direct Copper-Catalyzed alpha-Arylation of Benzyl Phenyl Ketones with Aryl Iodides, Route towards Tamoxifen,
Angew. Chem.-Int. Edit. 2012, 51, 12815
Michel Keller, Mykhailo Ianchuk, Sonia Ladeira, Marc Taillefer, Anne-Marie Caminade, Jean Pierre Majoral and Armelle Ouali
Synthesis of Dendritic beta-Diketones and Their Application in Copper-Catalyzed Diaryl Ether Formation,
Eur. J. Org. Chem. 20121056-1062
Anis Tlili, Florian Monnier and Marc Taillefer
Selective one-pot synthesis of symmetrical and unsymmetrical di- and triarylamines with a ligandless copper catalytic system,
Chem. Commun. 2012, 48, 6408-6410

2011

Marie-Agnès Lacour, Nicolas Rahier and Marc Taillefer
Mild and Efficient Trimethylsilylcyanation of Ketones Catalysed by PNP Chloride,
Chem.-Eur. J. 2011, 17, 12276-12279
Guillaume Lefèvre, Marc Taillefer, Carlo Adamo, Ilaria Ciofini and Anny Jutand
First Evidence of the Oxidative Addition of Fe0(N,N)2 to Aryl Halides, This Precondition Is Not a Guarantee of Efficient Iron-Catalysed C-N Cross-Coupling Reactions,
Eur. J. Org. Chem. 2011, 20-21, 3763-3780
Emilie Racine, Florian Monnier, Jean-Pierre Vors and Marc Taillefer
A Simple Copper-Catalyzed Synthesis of Tertiary Acyclic Amides,
Org. Lett. 2011, 13, 2818-2821

2010

Jean-Marc Campagne, Francine Agbossou, Tahar Ayad, Olivier Baudoin, Gérard Buono, Isabelle Chataigner, Christophe Crévisy, Isabelle Dez, Morgan Donnard, Fabienne Fache, Christian Feasson, Annie-Claude Gaumont, Laurent Giordano, Peter Hesemann, Francis Marsais, Marc Mauduit, Véronique Michelet, André Mortreux, Phannarath Phansavath, Olivier Piva, Jean-Philippe Roblin, Jacques Rouden, Marc Taillefer, Patrick Toullec, Théophile Tschamber and Virginie Vidal
Towards a green molecular chemistry,
Actual Chim. 201014-27
Anis Tlili, Florian Monnier and Marc Taillefer
Selective One-Pot Access to Symmetrical or Unsymmetrical Diaryl Ethers by Copper-Catalyzed Double Arylation of a Simple Oxygen Source,
Chem.-Eur. J. 2010, 16, 12299-12302
Sónia S. Nobre, Rute A S. Ferreira, Xavier Cattoën, Sofia Benyahya, Marc Taillefer, Verónica De Zea Bermudez, Michel Wong Chi Man and Luis D. Carlos
Lanthanide-Containing 2,2-Bipyridine Bridged Urea Cross-Linked Polysilsequioxanes,
Spectr. Lett. 2010, 43, 321-332

2009

Marie-Agnès Lacour, Maria Zablocka, Anne-Marie Caminade, Marc Taillefer and Jean Pierre Majoral
Design of phosphonium ended dendrimers bearing functionalized amines,
Tetrahedron Lett. 2009, 50, 4870-4873
Armelle Ouali, Jean Pierre Majoral, Anne-Marie Caminade and Marc Taillefer
NaOH-Promoted Hydrogen Transfer, Does NaOH or Traces of Transition Metals Catalyze the Reaction?,
ChemCatChem 2009, 1, 504-509
Anis Tlili, Ning Xia, Florian Monnier and Marc Taillefer
A Very Simple Copper-Catalyzed Synthesis of Phenols Employing Hydroxide Salts,
Angew. Chem.-Int. Edit. 2009, 48, 8725-8728
Hamid Kaddouri, Virginie Vicente, Armelle Ouali, Fouad Ouazzani and Marc Taillefer
Copper-Catalyzed Arylation of Nucleophiles by Using Butadienylphosphines as Ligands, Mechanistic Insight,
Angew. Chem.-Int. Edit. 2009, 48, 333-336
Ning Xia and Marc Taillefer
A Very Simple Copper-Catalyzed Synthesis of Anilines by Employing Aqueous Ammonia,
Angew. Chem.-Int. Edit. 2009, 48, 337-339
Florian Monnier and Marc Taillefer
Recent Advances in Catalytic C-C, C-N and C-O Ullmann-Type Coupling Reactions,
Angew. Chem.-Int. Edit. 2009, 48, 6954-6971
Sofia Benyahya, Florian Monnier, Michel Wong Chi Man, Catherine Bied, Fouad Ouazzani and Marc Taillefer
Sol-gel immobilized and reusable copper-catalyst for arylation of phenols from aryl bromides,
Green Chem. 2009, 11, 1121-1123

2008

Ning Xia and Marc Taillefer
Copper- or Iron-Catalyzed Arylation of Phenols from respectively Aryl Chlorides and Aryl Iodides,
Chem.-Eur. J. 2008, 14, 6037-6039
Marc Taillefer, Nicolas Rahier, Marie-Agnès Lacour and Jean-Noël Volle
Reactivity of Ph3PNLi towards PIII and PIV phosphorus electrophiles,
Tetrahedron 2008, 64, 6645-6650
Gennady Oshovsky, Armelle Ouali, Ning Xia, Maria Zablocka, René Boeré, Carine Duhayon, Marc Taillefer and Jean Pierre Majoral
Thiazolyl Phosphine Ligands for Copper-Catalyzed Arylation and Vinylation of Nucleophiles in Organic and Aqueous Media,
Organometallics 2008, 27, 5733-5736
Mounir Mansour, Roberto Giacovazzi, Armelle Ouali, Marc Taillefer and Anny Jutand
Activation of aryl halides by Cu(0)/1,10-phenanthroline, Cu(0) as precursor of Cu(I) catalyst in cross-coupling reactions,
Chem. Commun. 20086051-6053
Marie-Agnès Lacour, Maria Zablocka, Carine Duhayon, Jean Pierre Majoral and Marc Taillefer
Efficient Phosphorus Catalysts for the Halogen-Exchange (Halex) Reaction,
Adv. Synth. Catal. 2008, 350, 2677-2682
Florian Monnier, Marc Taillefer, Francois Turtaut and Leslie Duroure
Copper-Catalyzed Sonogashira-Type Reactions Under Mild Palladium-Free Conditions,
Org. Lett. 2008, 10, 3203-3206
Catherine Bied, Michel Wong Chi Man, Sofia Benyahya, Florian Monnier, Marc Taillefer and Fouad Ouazzani
Efficient and Versatile Sol-Gel Immobilized Copper Catalyst for Ullmann Arylation of Phenols,
Adv. Synth. Catal. 2008, 350, 2205-2208
Florian Monnier and Marc Taillefer
Catalytic CC, CN, and CO Ullmann-Type Coupling Reactions, Copper Makes a Difference,
Angew. Chem.-Int. Edit. 2008, 47, 3096-3099

2007

Marc Taillefer, Armelle Ouali and Ning Xia
A Novel and Efficient Iron-Copper Co-Catalyzed Arylation of Nitrogen Nuceophiles,
Angew. Chem.-Int. Edit. 2007, 46/6, 934-936
Armelle Ouali, Marc Taillefer, Jean François Spindler and Anny Jutand
Precatalysts involved in copper-catalyzed arylations of nucleophiles,
Organometallics 2007, 26, 65
Armelle Ouali, Jean François Spindler, Anny Jutand and Marc Taillefer
Nitrogen Ligands in Copper-Catalyzed Arylation of Phenols, Structure/Activity Relationships and Application,
Adv. Synth. Catal. 2007, 349, 1906
Tahar Abbaz, Abdel-K Gouasmia, Hideki Fujiwara, Takashi Hiraoka, Toyonari Sugimoto, Marc Taillefer and Jean-Marc Fabre
New TTF and bis-TTF containing thiophene units, Electrical properties of the resulting salts,
Synth. Met. 2007, 157, 508-516

2006

Marc Taillefer, Nicolas Rahier, Aurelien Hameau and Jean-Noel Volle
A new and convenient method for the synthesis of strong non-ionic bases,
Chem. Commun. 20063238-3239
Marc Taillefer, Armelle Ouali, Brice Renard and Jean-francis Spindler
Mild copper-catalyzed vinylation reactions of azoles and phenols with vinyl bromides,
Chem.-Eur. J. 2006, 12, 5301-5313
Armelle Ouali, Jean-francis Spindler, Henri-Jean Cristau and Marc Taillefer
Mild conditions for copper-catalyzed coupling reaction of phenols and aryl iodides and bromides,
Adv. Synth. Catal. 2006, 348, 499-505
Armelle Ouali, Regis Laurent, Anne-Marie Caminade, Jean-Pierre Majoral and Marc Taillefer
Enhanced Catalytic Properties of Copper in O- and N-Arylation and Vinylation Reactions, Using Phosphorus Dendrimers as Ligands,
J. Am. Chem. Soc. 2006, 128, 15990-15991

2005

Henri-Jean Cristau, Armelle Ouali, Jean-francis Spindler and Marc Taillefer
Mild and efficient copper-catalyzed cyanation of aryl iodides and bromides,
Chem.-Eur. J. 2005, 11, 2483-2492

2004

Virginie Vicente, Alain Fruchier, Marc Taillefer, Corinne Combes-Chamalet, Ian J. Scowen, Francoise Plenat and Henri-Jean Cristau
Synthesis and structural studies (1H, 13C, 31P NMR and X-ray) of new C-bonded cyclotriphosphazenes with heterocyclic substituents from novel phosphinic acid derivatives,
New J. Chem. 2004, 28, 418-424
Nicolas Inguimbert, Lothar Jaeger, Marc Taillefer, Matthias Biedermann and Henri-Jean Cristau
Synthesis of 1,3,5,2l5-triazaphosphinines by intramolecular cyclisation of (N-cyanophosphorimidoyl)guanidines and diguanidinophosphonium chlorides,
Eur. J. Org. Chem. 20044870-4876
Henri-Jean Cristau, Alain Fruchier, Francoise Plenat, Marc Taillefer and Virginie Vicente
Cyclophosphazenes with P-C bond(s) I - syntheses and reactivity,
Phosphazenes 2004931-981
Henri-Jean Cristau, Alain Fruchier, Francoise Plenat, Marc Taillefer and Virginie Vicente
Cyclophosphazenes with P-C bond(s) II - NMR- complexing properties,
Phosphazenes 2004983-1023
Henri-Jean Cristau, Pascal P. Cellier, Jean-francis Spindler and Marc Taillefer
Mild conditions for copper-catalyzed N-arylation of pyrazoles,
Eur. J. Org. Chem. 2004695-709
Henri-Jean Cristau, Pascal P. Cellier, Jean-francis Spindler and Marc Taillefer
Highly efficient and mild copper-catalyzed N- and C-arylations with aryl bromides and iodides,
Chem.-Eur. J. 2004, 10, 5607-5622
Henri-Jean Cristau, Pascal P. Cellier, Samy Hamada, Jean-francis Spindler and Marc Taillefer
A general and mild Ullmann-type synthesis of diaryl ethers,
Org. Lett. 2004, 6, 913-916

2003

Marc Taillefer and Henri-Jean Cristau
New trends in ylide chemistry,
Top. Curr. Chem. 2003, 229, 41-73
Pascal P. Cellier, Jean-francis Spindler, Marc Taillefer and Henri-Jean Cristau
Pd/C-catalyzed room-temperature hydrodehalogenation of aryl halides with hydrazine hydrochloride,
Tetrahedron Lett. 2003, 44, 7191-7195

2002

Marc Taillefer, Nicolas Rahier, Ewelina Minta and Henri-Jean Cristau
New applications of Ph3P:N-Li in organic synthesis and heteroatom chemistry,
Phosphorus, Sulfur and Silicon and the Related Elements 2002, 177, 1847-1850
Marc Taillefer, Victor Maurizot, Lothar Jager, Nicolas Inguimbert and Henri-Jean Cristau
Diazadiylide anions [Ph2P(NR)2]- (R = CN, C(O)Ph) as ambident bridging and chelating ligands,
Phosphorus, Sulfur and Silicon and the Related Elements 2002, 177, 2187-2188
V. Maurizot, L. Jager, A. Kolbe, C. Wagner, M. Taillefer and H J. Cristau
Crystal and molecular structure of the resonance stabilized azaylide Ph2P[NC(O)Ph]NHC(O)Ph and its IR spectroscopic characterization,
J. Mol. Struct. 2002, 609, 109-114
Henri Jean Cristau, Marc Taillefer and Nicolas Rahier
Lithium phosphonium azayldiides R3P:NLi. Applications in organic synthesis and coordination chemistry,
J. Organomet. Chem. 2002, 646, 94-106

2001

M. Taillefer, H J. Cristau, A. Fruchier and V. Vicente
Reactivity of lithium diphenylphosphonium diylides towards phosphorus electrophiles, Synthesis of a,b-unsaturated phosphorus compounds,
J. Organomet. Chem. 2001, 624, 307
L. Jaeger, V. Maurizot, C. Wagner, M. Taillefer and H J. Cristau
Reactivity of functionalized diazadiylides [Ph2P(NX)2] with X = C(O)Ph, CN,
Monograph Series of the International Conferences on Coordination Chemistry held periodically at Smolenice in Slovakia 2001, 5, 195-200
Henri-Jean Cristau, Marc Taillefer and Isabelle Jouanin
Synthesis of stabilized diaminophosphonium diazaylides,
Synthesis 200169-74

2000

N. Inguimbert, M. Biedermann, H. Stoeckli-Evans, H. Hartung, A. Kolbe, L. Jager, M. Taillefer and H J. Cristau
Crystal and molecular structures of N-diphenylphosphinyl- and N-diphenylthiophosphinyl-N'-phenyl guanidines, Ph2P(Y)N:C(NH2)NHPh (Y = O,S),
J. Mol. Struct. 2000, 519, 211-218
Henri Jean Cristau, Rachel Vogel, Marc Taillefer and Alain Gadras
A novel and efficient arylation of malononitrile catalyzed by nickel(0) complexes,
Tetrahedron Lett. 2000, 41, 8457-8460

2019

Marc Taillefer,
Studies Towards Transition-Metal Catalyzed C-C and C-N Bond Formation,
«Invitation Wuhan University – Yangtze Academic Forum - Conférence honorifique», Wuhan, février 2019,

2018

Marc Taillefer,
C-C and C-Heteroatome bond formation by Cu or Fe catalysis or mediated in metal free conditions. Recent advances and future prospects.,
«International Conference on Chemistry for Human Development (ICCHD-2018)», Calcutta (Inde), janvier 2018,
Marc Taillefer,
C-C and C-Heteroatome bond formation by Cu or Fe catalysis or mediated in metal free conditions: From Academic discovery to industrial application.,
«NoNoMetCat Woorkshop», Rostock, septembre 2018,
Marc Taillefer,
Formation de liaisons C-C et C-Hétéroatome par catalyse au Cuivre ou au Fe. De la découverte scientifique aux mécanismes et aux applications industrielles.,
«Invitation de l'Académie des Sciences, Institut de France», Paris, septembre 2018,

2017

Marc Taillefer,
-C and C-Heteroatome bond formation by Cu or Fe catalysis or mediated in metal free conditions. From Academic discovery to industrial application.,
«Beilstein Symposium. Tomorrow’s catalysis for research and industry», Potsdam, Germany, octobre 2017,
Marc Taillefer,
Copper-, Iron catalyzed N- O- and C-arylation of nucleophiles: Academic discovery, mechanism and industrial application.,
«BIT’s 8TH Annual Global Congress of catalysis», Shanghai, octobre 2017,
Marc Taillefer,
Copper-, Iron catalysed N- O- and C-arylation of nucleophiles: From Academic discovery to industrial application.,
«World Chem Conference.», Rome, septembre 2017,

2016

Marc Taillefer,
Cu, Fe or Metal Free Catalysed Arylation of Nucleophiles, Advances, Future Prospects, Industrial Applications.,
«Servier – Conférencier académique extérieur invité pour la journée scientifique annuelle de Servier (regroupant tous les sites mondiaux)», Bolbec, avril 2016,
Marc Taillefer,
Copper-, Iron N- O- and C-arylation of nucleophiles: Recent advances and future prospects.,
«Novena Trobada de Joves Investigadors dels Països Catalans», Perpignan, France, février 2016,

2015

Marc Taillefer,
Metal catalyzed arylation of nucleophiles: recent progress, mechanistic insight and industrial applications.,
«SILQCOM / BRWS 2015. Latin American symposium on coordination and organometallic chemisty.», Rio de Jianero (Brésil), octobre 2015,
Marc Taillefer,
Metal catalysed arylation of nucleophiles. Academic discovery, mécanistic insights and industrial applications.,
«XXXV Biannual Meeting RSEQ.», A Coruna (Espagne), avril 2015,
Marc Taillefer,
Metal catalysed arylation of nucleophiles. From Academic discovery to industrial application at large scale.,
«Invitation par l'American Chemical Society (ACS) pour donner une conférence plénière à la journée commémorative du 10em anniversaire de l'ACS Green Chemistry Institute Pharmaceutical Roundtable (Hoffmann-La Roche, Suisse)», Bâle, avril 2015,

2014

Marc Taillefer,
Metal catalysed arylation of nucleophiles.,
«Congrés Franco-Japonais.», Lyon, octobre 2014,
Marc Taillefer,
Copper-, Iron N- O- and C-arylation of nucleophiles: Recent advances and future prospects.,
«Congrés Franco-Roumain.», Montpellier, octobre 2014,
Marc Taillefer,
Metal catalysed arylation of nucleophiles and sustainable chemistry.,
«Workshop on Cost Efficient Metal Catalysis - Syngenta», Stein (suisse) - Syngenta, avril 2014,

2012

Marc Taillefer,
Copper-, Iron N- O- and C-arylation of nucleophiles: Recent advances and future prospects,
«Gordon Conference Organic Reaction and Processes 2012», Bryant University (USA), 15 juillet - 20 août 2012,

2011

Marc Taillefer,
Metal catalysed arylation of nucleophiles,
«The 16th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis. OMCOS16», Shanghai (Chine), 24-28 juillet 2011,

2010

Marc Taillefer,
Copper-, Iron N- O- and C-arylation of nucleophiles: Recent advances and future prospects,
«6th Asian-European Symposium on Metal-Mediated Efficient Organic Synthesis.», Singapore, 7-9 juin 2010,

2009

Marc Taillefer,
Iron- or Cu-catalyzed arylation of nucleophiles : Recent Progress and Mechanistic Insight,
«SECO 46 la Rochelle», La Rochelle, France, 25-29 mai 2009,

2008

Marc Taillefer,
Copper-, Iron N- O- and C-arylation of nucleophiles: Recent advances and future prospects.,
«International Congres on Organometallics and Catalysis. ICOMC», Rennes, 13-18 juillet 2008,

Marc Taillefer, ,
Iron- or Copper-catalyzed arylation of nucleophiles : recent progress and mechanistic insight
«International conference on organometallic chemistry», Rennes, France, 13-18 juillet 2008,
Marc Taillefer,
Copper-, Nickel-, or Iron catalyzed N- O- and C- Arylation of Nucleophiles: New Advances and Future Prospects
«China-France Workshop / Molecular Catalysts and Catalysis», Rennes / France, 18-21 juillet 2006,
Marc Taillefer,
copper-, Nickel-, or Iron catalyzed N- O- and C- Arylation of Nucleophiles: New Advances and Future Prospects
«1st European Chemistry Congres», Budapest, 27-31 juin 2006,
Marc Taillefer,
Copper-, Nickel-, or Iron catalyzed N- O- and C- Arylation of Nucleophiles: New Advances and Future Prospects copper-, Nickel-, or Iron catalyzed N- O- and C- Arylation of Nucleophiles: New Advances and Future Prospects
«Journées de la division de chimie de coordination», Toulouse (France), 3-4 avril 2006,
Marc Taillefer, A. Ouali, J.F. Spindler,
Arylations de nucléophiles catalysées par le cuivre: vers une meilleure compréhension du mécanisme mis en jeu.
«SFC - Journées de la division de chimie de coordination», Toulouse, France, 3-4 avril 2006,

2017

Kathrin Junge, Gerrit Wienhöfer, Mathias Beller, Anis Tlili, Gwilherm Evano, Marc Taillefer, Rhett Kempe, Christoph Malbertz and Jurgen Klankermayer
New Trends in Organometallic Catalysts,
Applied Homogeneous Catalysis with Organometallic Compounds: A Comprehensive Handbook in Three Volumes, Third Edition,
Éditions Boy Cornils, Wolfgang A. Herrmann, Matthias Beller, Rocco Paccielo, , 2017.

2013

Anis Tlili and Marc Taillefer
Ullmann Condensation Today, Arylation of Alcohols and Thiols with Aryl Halides, 41-91
Copper-Mediated Cross-Coupling Reactions,
Éditions Gwilherm Evano, Nicolas Blanchard, , 2013.
Florian Monnier and Marc Taillefer
Copper-Catalyzed C(aryl)-N Bond Formation, 173-204
Topics in Organometallic Chemistry,
Éditions Springer Berlin Heidelberg, , 2013.

espaceur 2016

Catalytic system for cross-coupling reactions
M. Taillefer,
US 9272274(2016)
Déposé par: CNRS, SATT AXLR

espaceur 2013

Process for creating carbon-carbon bonds using carbonyl compounds.
M. Taillefer, A. Tlili, G. Danoun,
WO2013182640(2013)
Déposé par: CNRS,

espaceur 2012

Procédé de synthèse de phosphine
M. Taillefer, L.Routaboul, A.C.Gaumont
FR1058295(2012); PCT/FR2011/052380(2012)
Déposé par: CNRS,
Procédé de synthèse de biaryléthers ou bihétéroaryléthers
F. Monnier, M. Taillefer, A. Tlili,
FR10 57099(2012); PCT/FR2011/052044(2012)
Déposé par: CNRS, ENSCM

espaceur 2010

Procédé d'hydroxylation de composés arylés halogénés
F. Monnier, M. Taillefer, A. Tlili, N. Xia,
FR09/02767(2010)
Déposé par: CNRS,
Procédé de catalyse de réactions de transfert d'hydrogène
M. Taillefer, A.Ouali, A.M. Caminade, JP Majoral
FR200903076(2010)
Déposé par: CNRS,
New catalytic system for cross-coupling reactions
F. Monnier, M. Taillefer, A. Tlili, N. Xia,
US20070996830(2010)
Déposé par: CNRS,

espaceur 2009

Procédé de synthèse d'arylamine
M. Taillefer, N. Xia,
Fr 0706827(2009); PCT/FR2008/051710(2008)
Déposé par: CNRS,

espaceur 2008

Procédé de préparation de ligands de type phosphines butadiéniques, leurs complexes avec le cuivre, et leurs applications en catalyse
M. Taillefer, H. Kaddouri, A. Ouali, F. Ouazzani
Fr 07 02878(2008); PCT/IB2008/ 000984(2008)
Déposé par: CNRS, ENSCM, Université Sidi Mohammed Ben Abdellah (MA)
Utilisation de complexes cuivre/phosphines cyclovinyliques comme catalyseurs d'arylation
M. Taillefer, H. Kaddouri, F. Ouazzani
Fr 07 06826(2008); PCT/IB2008051736(2008)
Déposé par: CNRS, ENSCM
Efficient iron/copper co-catalyzed process for carbon-carbon or carbon-heteroatom bonding
M. Taillefer, N. Xia, A. Ouali
US20060818334(2008); PCT/IB2007/001836(2008)
Déposé par: CNRS, ENSCM

Institut Charles Gerhardt Montpellier - Direction

UMR 5253 - CNRS/UM/ENSCM

Pôle Chimie Balard Recherche
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Tel: +33 (0)4 67 61 36 14
Email: direction@icgm.fr

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